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In the title compound, [Co(C20H12O6)(C18H18N4)] n , the Co(II) atom, located on a twofold rotation axis, is hexa-coordinated to four O from two bis-bidentate 4,4'-[phenyl-enebis(-oxy)]dibenzoate (L) ligands and two N atoms from two 1,1'-(butane-1,4-di-yl)bis-(1H-benzimidazole) (bbbm) ligands, forming a distorted octahedral cis-N2O4 coordination environment. Polymeric zigzag chains along [102] are built up by the bridging L ligands. These chains are additionally connected by the bbbm ligands to produce a two-dimensional coordination polymer parallel too (010).

acta crystallographica. section e, crystallographic communications

Crystal structure of poly[[μ-1,1′-(butane-1,4-diyl)bis(1H-benzimidazole)-κ2N3:N3′]{μ-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4O,O′:O′′,O′′′}cobalt(II)]