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In the title compound, C7H5NO4, the nitro group and the aldehyde group are inclined to the benzene ring by 16.6 (3) and 15.6 (3)°, respectively. In the crystal, mol-ecules are linked via O-H⋯O hydrogen bonds, forming chains along [100]. The chains are linked by C-H⋯O hydrogen bonds, forming a three-dimensional structure.

Cystal structre of 5-hydroxy-2-nitrobenzaldehyde