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In the title compound, [Cu2(OH)2(C12H8N2)2(H2O)2](C12H6O4)·6H2O, the two hydroxide groups bridge the two Cu(II) cations, forming a centrosymmetric binuclear complex cation, in which the Cu(II) cation is coordinated by a 1,10-phenanthroline (phen) mol-ecule, one water mol-ecule and two bridging hydroxide O atoms in a distorted N2O3 square-pyramidal coordination geometry. The naphthalene-2,6-di-carboxyl-ate anion is also located on an inversion centre. In the crystal, O-H⋯O hydrogen bonds link the cations, anions and lattice water mol-ecules into a three-dimensional supra-molecular architecture. Extensive π-π stacking is observed between the parallel or nearly parallel aromatic rings of adjacent phen ligands and naphthalenedi-carboxyl-ate anions, the centroid-to-centroid distances ranging from 3.4990 (16) to 3.8895 (16) Å.

Crystal structure of di-μ-hydroxido-bis[aqua(1,10-phenanthroline-κ2N,N′)copper(II)] naphthalene-2,6-dicarboxylate hexahydrate

Crystal structure of di-μ-hydroxido-bis[aqua(1,10-phenanthroline-κ²N,N′)copper(II)] naphthalene-2,6-dicarboxylate hexahydrate