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The title polynuclear organometallic titanium(IV) oxide, [{Ti 3 (η 5 -C 5 Me 5 ) 3 (μ-O) 4 } 2 (μ-O)], exhibits two Ti 3 O 4  cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a penta­methyl­cyclo­penta­dienyl ligand linked in an η 5 -coordination fashion, while three bridging O atoms fill the other three sites.

acta crystallographica. section e, crystallographic communications

Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}