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The five-coordinate Cu(II) atom in the title complex [CuCl2(C16H19N3)]·0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu-Cl distance is 0.2626 (6) Å longer than the basal Cu-Cl distance. Weak C-H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitro-gen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

acta crystallographica. section e, crystallographic communications

Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ3N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate