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The asymmetric unit of the title salt, [C 22 H 20 O 2 P] 2   + [TeI 6 ] 2− , consists of one triphenyl(5-oxooxolan-3-yl)phosphanium cation and one half of a hexa­iodido­tellurate(IV) dianion. The Te atom is located at an inversion centre and is octa­hedrally coordinated by six I atoms. The Te—I bond lengths range from 2.9255 (9) to 2.9439 (10) Å. The I—Te—I angles between  cis -iodide ligands are in the range 87.85 (3)–92.15 (3)°. In the crystal, the components are connected by C—H⋯I inter­actions. In the final refinement of the compound a void of 32 Å 3  was observed.

Crystal structure of bis[(5-oxooxolan-3-yl)triphenylphosphanium] hexaiodidotellurate(IV)