English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

In the title compound, [Rh(C6H5N4)Cl2(C12H27P)2], the Rh(III) ion is chelated by the singly deprotonated 2,2'-biimidazolate (Hbim(-)) ligand and coordinated by two chloride ions and two tri-n-butyl-phosphane ligands. The chloride ions and N atoms of the Hbim(-) ligand lie in a plane where the sum of X-Rh-X angles between cis sites is 360°. The phosphane ligands occupy the sites perpendicular to the plane, completing the overall distorted octahedral coordination sphere. The complex forms a self-complementary hydrogen-bonded dimer with the inversion-related complex through N-H⋯N hydrogen bonds.

acta crystallographica. section e

Crystal structure of dichlorido[2-(1H-imidazol-2-yl-κN3)imidazolato-κN]bis(tri-n-butylphosphane-κP)rhodium(III)