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In the crystal structure of the title compound, [Zn(NCS)2(C12H10ClN)2], the Zn(2+) cation is N-coordinated by two terminally bonded thio-cyante anions and by two 4-(4-chloro-benz-yl)pyridine ligands within a slightly distorted tetra-hedron. The asymmetric unit consists of half of the discrete complex, the central Zn(2+) cation of which is located on a twofold rotation axis. The discrete complexes are linked into layers via a weak inter-molecular hydrogen-bonding inter-action, with a H⋯Cl distance of 2.85 Å and a C-H⋯Cl angle of 151°. These layers extend parallel to the ab plane and are held together by dispersion forces only.

Crystal structure of bis[4-(4-chlorobenzyl)pyridine-κN]bis(thiocyanato-κN)zinc