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In the title compound, C 10 H 14 Br 4 O 5 , synthesized from the meth­oxy Schiff base  N -(pyridin-2-ylmeth­yl)meth­oxy­aniline and mol­ecular bromine, the cyclo­hexa­none ring has a chair conformation with one of the four meth­oxy groups equatorially orientated with respect to the carbonyl group and the others axially orientated. The C—Br bond lengthsvary from 1.942 (4) to1.964 (4) Å. In the crystal, weak C—H⋯O carbon­yl  hydrogen-bonding inter­actions generate chains extending along the  b -axis direction. Also present in the structure are two short inter­molecular Br⋯O meth­oxy  inter­actions [3.020 (3) and 3.073 (4) Å].

2,2,6,6-Tetrabromo-3,4,4,5-tetramethoxycyclohexanone