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In the title polymeric complex, {[Ag(C 11 H 11 N 3 )]PF 6 }  n  , the Ag I  ion is two-coordinated in a nearly linear coordination geometry [N—Ag—N = 175.98 (9)°] by two pyridine N atoms from two symmetry-related  N -[(pyridine-2-yl)meth­yl]pyridine-3-amine ligands. Each Ag I  ion is bridged by the ligands, forming a helical chain propagating along the  b- axis direction. The right- and left-handed helical chains are alternately arranged  via  Ag⋯Ag [3.2639 (5) Å] and π–π stacking inter­actions [centroid–centroid distance = 3.523 (1) Å], resulting in the formation of a two-dimensional supra­molecular network extending parallel to (101). Weak Ag⋯F inter­actions [longest Ag⋯F inter­action = 3.153 (2) Å], as well as N—H⋯F and C—H⋯F hydrogen-bonding inter­actions, occur between the helical chains and the anions.

catena-Poly[[silver(I)-μ-N-[(pyridin-2-yl)methyl]pyridine-3-amine-κ2N:N′] hexafluoridophosphate]

catena-Poly[[silver(I)-μ-N-[(pyridin-2-yl)methyl]pyridine-3-amine-κ²N:N′] hexafluoridophosphate]