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In the polymeric title compound, [Ag(C 8 H 14 N 3 )]  n  , the Ag I  cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The Ag I  cation deviates from the coordination plane by 0.014 (1) Å and the N—Ag—N bond angles are 96.85 (11), 97.72 (10) and 165.39 (12)°. The triazolate anion bridges three Ag I  cations, forming a three-dimensional polymeric network.

Poly[(μ3-3,5-diisopropyl-4H-1,2,4-triazolato-κ3N:N′:N′′)silver(I)]

Poly[(μ₃-3,5-diisopropyl-4H-1,2,4-triazolato-κ³N:N′:N′′)silver(I)]