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In the title complex, [Ni(NCS) 2 (C 6 H 6 N 2 O) 2 (H 2 O) 2 ], the Ni II  ion is located on an inversion center and is coordinated in a distorted octa­hedral environment by two N atoms from two nicotinamide ligands and two water mol­ecules in the equatorial plane, and two N atoms from two thio­cyanate anions in the axial positions, all acting as monodentate ligands. In the crystal, weak N—H⋯S hydrogen bonds between the amino groups and the thio­cyanate anions form an  R   4   2 (8) motif. The complex mol­ecules are linked by O—H⋯O, O—H⋯S, and N—H⋯S hydrogen bonds into a three-dimensional supra­molecular structure. Weak π–π inter­actions between the pyridine rings is also found [centroid–centroid distance = 3.8578 (14) Å].

Diaquabis(nicotinamide-κN1)bis(thiocyanato-κN)nickel(II)

Diaquabis(nicotinamide-κN¹)bis(thiocyanato-κN)nickel(II)