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The complete mol-ecule of the title complex, [Hg(C11H11N4O2S)2(C10H8N2)], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetra-hedral (from the N,N'-bidenate bi-pyridine mol-ecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (&gt; 2.80 Å) Hg-N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N-H⋯(N,O) and N-H⋯N hydrogen bonds link the mol-ecules into a three-dimensional network.

acta crystallographica. section e

Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II)