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The trinuclear title compound, [Fe 3 (C 3 H 6 S 2 ) 2 (CO) 7 ], is a mixed-valent Fe I /Fe II  complex and crystallizes with two mol­ecules of similar configuration in the asymmetric unit. The three Fe atoms in each mol­ecule display a bent arrangement [Fe—Fe—Fe = 156.22 (4) and 157.06 (3)°]. Both outer Fe I  atoms are six-coordinated in a distorted ocahedral coordination geometry defined by the bridging Fe II  atom, three carbonyl C atoms and two bridging S atoms. The coordination number of the central Fe II  atom is seven and includes bonding to the two outer Fe I  atoms, four bridging S atoms and one carbonyl C atom. The resulting coordination polyhedron might be described as a highly distorted monocapped trigonal prism. In the crystal packing, the mol­ecules exhibit a chain-like arrangement parallel to [100] and [001], and the resulting layers are stacked along [010]. The cohesion of the structure is dominated by van der Waals inter­actions.

Heptacarbonylbis(μ-propane-1,3-dithiolato)triiron(I,II)(2Fe—Fe)