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In the title compound, [Zn(C 11 H 7 N 6 ) 2 (H 2 O) 2 ], the Zn II  cation, located on an inversion center, is  N , N ′-chelated by two 5-(pyrazin-2-yl)-3-(pyridin-3-yl)-1,2,4-triazolide anions and is further coordinated by two water mol­ecules in a distorted N 4 O 2  octa­hedral geometry. In the anionic ligand, the pyrazine and pyridine rings are twisted with respect to the central triazole ring by 5.77 (10) and 11.54 (10)°, respectively. In the crystal, classical O—H⋯N and weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between aromatic rings [the centroid–centroid distances between triazole and pyrazine rings, and between triazole and pyridine rings are 3.623 (2) and 3.852 (2) Å, respectively] connect the mol­ecules into a three-dimensional supra­molecular architecture.

Diaquabis[5-(pyrazin-2-yl-κN1)-3-(pyridin-3-yl)-1,2,4-triazolido-κN1]zinc

Diaquabis[5-(pyrazin-2-yl-κN¹)-3-(pyridin-3-yl)-1,2,4-triazolido-κN¹]zinc