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The title compound, C 22 H 20 Br 2 N 2 S, was synthesized under solvent-free conditions. The mol­ecule shows crystallographic  C   2  symmetry, with the S atom of the central thio­phene ring lying on a twofold rotation axis. Furthermore, as a consequence of the ( S , S ) stereochemistry, the mol­ecule has a twisted conformation. The dihedral angle between the thio­phene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, mol­ecules are arranged in a chevron-like pattern, without any significant inter­molecular inter­actions.

2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene