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In the title complex, [CuCl(C 8 H 8 N 2 OS)(C 18 H 15 P) 2 ]·2CH 3 OH, the Cu I  ion is coordinated by one chloride anion, one S atom from the 5-meth­oxy-1 H -benzimidazole-2(3 H )-thione ligand and two P atoms from two tri­phenyl­phosphine ligands in a distorted tetra­hedral geometry. One of the N-bound H atoms is involved in an intra­molecular N—H⋯Cl hydrogen bond, while another one inter­acts with the solvent methanol mol­ecule  via  an N—H⋯O hydrogen bond. Inter­molecular O—H⋯Cl and O—H⋯O hydrogen bonds link two further complex mol­ecules and four solvent mol­ecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π inter­actions.

Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate