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In the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2·2C3H6O, the binuclear Ru(II) complex dication, [{RuCl(η(6)-cym)}2(μ-tape)](2+), built up by a planar 1,6,7,12-tetra-aza-perylene (tape) bridge, two η(6)-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The Ru(II) atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexa-fluorido-phosphate anion and the asymmetric unit is completed by an acetone mol-ecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C-H⋯O/F/Cl inter-actions.

acta crystallographica. section e

μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate