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The title compound, [Bi(C 4 H 8 NOS 2 ) 2 I(C 12 H 8 N 2 )], is monomeric, with the Bi III  atom chelated by the two S atoms of two morpholine-4-carbodi­thio­ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi III  atom adopting a highly distorted monocapped octa­hedral geometry.

Iodidobis(morpholine-4-carbodithioato-κ2S,S′)(1,10-phenanthroline-κ2N,N′)bismuth(III)

Iodidobis(morpholine-4-carbodithioato-κ²S,S′)(1,10-phenanthroline-κ²N,N′)bismuth(III)