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In the title compound, [K 2 (C 7 H 3 Cl 2 O 2 ) 2 (H 2 O)]  n  , the potassium salt of 2,4-di­chloro­benzoic acid, the repeating unit in the polymeric structure consists of two identical irregular KO 6 Cl units related by twofold rotational symmetry, linked by a bridging water mol­ecule lying on the twofold axis. The coordination polyhedron about the K +  ion comprises a carboxyl­ate O atom and a Cl-atom donor from a bidentate chelate ligand inter­action, four O-atom donors from a doubly bridging bidentate carboxyl­ate  O , O ′-chelate inter­action and the water mol­ecule. A two-dimensional polymeric structure lying parallel to (100) is generated through a series of conjoined cyclic bridges between K +  ions and is stabilized by water–carboxyl­ate O—H⋯O hydrogen-bonding inter­actions.

Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium]

Poly[μ-aqua-bis(μ₅-2,4-dichlorobenzoato)dipotassium]