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The title dinuclear half-sandwich complex, [CpTi(OCH=CH 2 )(μ 2 -N- i Pr)] 2  (Cp = cyclo­penta­dien­yl;  i Pr = isopropyl), was ob­tained from the reaction of Cp 2 TiCl 2 ,  n -butyl­lithium and iso­propyl­amine in tetra­hydro­furan. Each Ti IV  atom is coordinated by one Cp ligand, one vin­yloxy unit and two bridging imido groups in a strongly distorted tetra­hedral geometry. There are two half mol­ecules in the asymmetric unit, such that whole mol­ecules being generated by inversion symmetry.

Bis(μ2-isopropylimido-κ2 N:N)bis[(η5-cyclopentadienyl)(ethenolato-κO)titanium(IV)]

Bis(μ₂-isopropylimido-κ² N:N)bis[(η⁵-cyclopentadienyl)(ethenolato-κO)titanium(IV)]