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In the title complex, [Ni(C6H9N2O3S)2(H2O)2]·2H2O, the Ni(II) atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazole-sulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octa-hedral configuration. The crystal structure displays O-H⋯O and N-H⋯O hydrogen bonds, which connect the components into an extended three-dimensional network.

Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ2 N 3,O)nickel(II) dihydrate

Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ² N ³,O)nickel(II) dihydrate