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The title solvated Schiff base compound, C 25 H 26 N 2 O 4 ·CH 3 CN, possesses an O 2 N 2  donor set affording a potentially tetra­dentate metal complex ligand. The central ring makes dihedral angles of 6.7 (3) and 48.4 (2)° with the pendant rings. Intra­molecular N—H⋯O hydrogen-bonding inter­actions are observed.

6,6′-Diethoxy-2,2′-[4-methyl-1,2-phenylenebis(nitrilomethanylylidene)]diphenol acetonitrile monosolvate