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In the title compound, [CoRu(C 5 H 5 )(C 16 H 9 )(C 17 H 14 P) 2 ]PF 6 , the Ru II  atom is coordinated by a cyclo­penta­dienyl ring in an η 5 -mode, one C atom from a 4,4′-diethynyl-1,1′-biphenyl ligand and two P atoms from a chelating 1,1′-bis­(di­phenyl­phosphan­yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C—H⋯F hydrogen bonds link the complex cations and hexa­fluorido­phosphate anions into a three-dimensional supra­molecular structure.

acta crystallographica. section e

[1,1′-Bis(diphenylphosphanyl)cobaltocenium-κ2P,P′](η5-cyclopentadienyl){2-[4-(4-ethynylphenyl)phenyl]ethynyl-κC}ruthenium(II) hexafluoridophosphate