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The asymmetric unit of the title co-crystal, C 12 H 14 N 4 O 2 S·0.5C 6 H 12 N 2 , comprises the sulfonamide mol­ecule and half a mol­ecule of 1,4-di­aza­bicyclo­[2.2.2]octane (DABCO), the latter being disposed about a crystallographic twofold rotation axis. In the sulfonamide mol­ecule, the aromatic rings are almost perpendicular to one another [dihedral angle = 75.01 (8)°]. In the crystal, mol­ecules are connected into a three-mol­ecule aggregate  via  amide–DABCO N—H⋯N hydrogen bonds, and these are connected into a three-dimensional architecture  via  amino–DABCO N—H⋯O and amino-pyrimidine N—H⋯N hydrogen bonds.

4-Amino-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide–1,4-diazabicyclo[2.2.2]octane (2/1)