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In the title salt, [Ni(C 12 H 14 N 6 O) 2 ](CF 3 SO 3 ) 2 ·2CH 3 OH, the Ni II  ion is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni II  ion is situated on an inversion centre. The Ni—N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N—Ni—N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N—Ni—N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O—H⋯O hydrogen bonds between methanol solvent mol­ecules and tri­fluoro­methane­sulfonate anions are observed.

Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN2)ethane]nickel(II) bis(trifluoromethanesulfonate) methanol disolvate

Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN²)ethane]nickel(II) bis(trifluoromethanesulfonate) methanol disolvate