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In the title salt, C 14 H 13 Br 3 NOS 2   + ·Br − , synthesized by bromination of mesoionic 2-[2-(piperidin-1-yl)-1,3-di­thiol-2-ylium-4-yl]phenolate in glacial acetic acid, the dihedral angle between the 1,3-di­thiol­ium ring and the phenolic substituent ring is 45.9 (3)° due to the steric influence of the  ortho -Br group on the 1,3-di­thiol­ium ring. The piperidine ring adopts a chair conformation. In the crystal, the cation and anion are linked by an O—H⋯Br hydrogen bond.

5-Bromo-4-(3,5-dibromo-2-hydroxyphenyl)-2-(piperidin-1-yl)-1,3-dithiol-2-ylium bromide