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The title complex, [Co 2 (C 8 H 5 NO 4 S) 2 (C 10 H 8 N 2 ) 3 (H 2 O) 2 ]·1.3H 2 O, was synthesized under hydro­thermal conditions. The Co II  ion is six-coordinated in a slightly distorted octa­hedral environment resulting from two carboxyl­ate O atoms of two 2-carb­oxy­methyl­sulfanyl nicotinate (2-CMSN 2− ) anions, one water mol­ecule and three N atoms of three 4,4′-bi­pyridine ligands, with one 4,4′-bi­pyridine ligand situated on a centre of inversion. Two neighboring Co II  ions are linked by two anions, giving a dinuclear [Co 2 (2-CMSN) 2 ] subunit with a Co⋯Co separation of 6.8600 (3) Å. The dinuclear subunits are joined by bridging 4,4′-bi­pyridine linkers, generating a three-dimensional network structure. Disordered water mol­ecules are situated in the free space of this network. O—H⋯O hydrogen bonding within and between the subunits enhances the stability of the structure.

Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate]

Poly[[diaquatris(μ₂-4,4′-bipyridine)bis[μ₂-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate]