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In the title compound, (C 8 H 12 N) 3 [Sb 2 Br 9 ], two of the three unique  N , N -dimethyanilinium cations exhibit flip–flop disorder with an occupancy ratio of 0.58 (1):0.42 (1). N—H⋯Br hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network.

Tris(N,N-dimethylanilinium) tri-μ-bromido-bis[tribromidoantimonate(III)]