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The title salt, (C 6 H 14 N 2 ) 2 [Sb 2 Cl 10 ]·2H 2 O, was obtained by slow evaporation of an acidic solution of 1,4-di­aza­bicyclo­[2.2.2]octane and SbCl 3 . The crystal structure consists of (C 6 H 14 N 2 ) 2+  cations, [Sb 2 Cl 10 ] 4−  double octa­hedra and lattice water mol­ecules. All mol­ecular components are situated on special positions. The cation and the lattice water mol­ecule exhibit mirror symmetry, whereas the anion has site symmetry 2/ m . The cations, anions and water mol­ecules are alternately arranged into columns along [010]. Individual columns are joined into layers extending along (001). Intra­layer N—H⋯O and inter­layer N—H⋯Cl hydrogen-bonding inter­actions lead to the formation of a three-dimensional network.

Bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridoantimonate(III)] dihydrate