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In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octa-hedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate di-pyridyldi-amine ligand, two O-atom donors from one of the carboxyl-ate groups of the bidentate chelating adipate ligand and two water mol-ecules. In addition, there are three solvent water mol-ecules which are involved in both intra- and inter-unit O-H⋯O hydrogen-bonding inter-actions, which together with an amine-water N-H⋯O hydrogen bond produce a three-dimensional framework.

(Adipato-κ2O,O′)diaqua[bis(pyridin-2-yl-κN)amine]cobalt(II) trihydrate

(Adipato-κ²O,O′)diaqua[bis(pyridin-2-yl-κN)amine]cobalt(II) trihydrate