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The title compound, C 13 H 11 N 3 S, crystallizes with two independent mol­ecules in the asymmetric unit. The two mol­ecules are geometrically very similar and differ mainly in a spatial orientation of the benzene and thieno[3,2- d ]pyrimidine ring systems [dihedral angles = 69.49 (4) and 79.05 (3)°]. The nine-membered thieno[3,2- d ]pyrimidine moieties have a planar conformation (r.m.s. deviations = 0.020 and 0.012 Å). In the crystal, mol­ecules are linked through N—H⋯N, N—H⋯C and C—H⋯π non-covalent contacts into chains along the  c  axis, while neighbouring chains are connected  via  C—H⋯N inter­actions.

N-Benzylthieno[3,2-d]pyrimidin-4-amine