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In the title Ru II  carboxyl­ate compound, [Ru(C 2 H 3 O 2 )(C 26 H 24 P 2 ) 2 ](CF 3 O 3 S) 0.75 Cl 0.25 , the distorted tris-bidentate octa­hedral stereochemistry about the Ru II  atom in the complex cation comprises four P-atom donors from two 1,2-bis­(diphenyl­phosphan­yl)ethane ligands [Ru—P = 2.2881 (13)–2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru—O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoro­methane­sulfonate anions and one chloride anion, with two such formula units in the unit cell.

acta crystallographica. section e

cis,cis,cis-(Acetato-κ2O,O′)bis[1,2-bis(diphenylphosphanyl)ethane-κ2P,P′]ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride