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The reaction of manganese seleno­cyanate with 1,2-bis­(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe) 2 (C 12 H 12 N 2 )(CH 3 OH) 2 ]·C 12 H 12 N 2 }  n  . The Mn II  cation is coordinated by two  N -bonded seleno­cyanate anions, two bpa ligands and two  O -bonded methanol mol­ecules, within a slightly distorted octa­hedral geometry. The Mn II  cations and the non-coordinating  N -donor ligands are located on centers of inversion while the coordinating  N -donor co-ligands are located on a twofold rotation axis. In the crystal, the Mn II  cations are linked into chains along the  c -axis direction by the bpa ligands. The chains are further connected  via  a non-coordinating bpa ligand into layers parallel to (3-10)  via  O—H⋯N hydrogen-bonding inter­actions.

acta crystallographica. section e

catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethane-κ2N:N′] 1,2-bis(pyridin-4-yl)ethane monosolvate]