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The title complex, {[Cu(C 21 H 13 N 5 S 2 )]PF 6 ·CH 3 CN}  n  , was formed immediately on adding together a methanol solution containing copper(I) ions and a methanol solution of 2,6-bis­[4-(pyridin-2-yl)thia­zol-2-yl]pyridine. Crystallographic studies of the complex reveal a coordination polymer with the ligand acting as a bis­(bidentate) ligand with the pyridine N atom not coordinating a metal centre. The Cu I  atom is four-coordinate with approximately tetra­hedral stereochemistry: the N 4  donor set is provided by bipyridine-like moieties of the two heterocyclic ligands. Parallel chains of the coordination polymer run along the  b -axis direction with the disordered (0.50:0.50 occupancy ratio) PF 6   −  anions and acetonitrile solvent mol­ecules located between the chains.

acta crystallographica. section e

<i>catena</i>-Poly[[copper(I)-μ-2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine] hexafluoridophosphate acetonitrile monosolvate] from single-crystal synchrotron data

catena-Poly[[copper(I)-μ-2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine] hexafluoridophosphate acetonitrile monosolvate] from single-crystal synchrotron data