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In the title compound, {[Zn(C 8 H 4 O 4 )(C 6 H 6 N 2 O) 2 ]·C 6 H 6 N 2 O}  n  , the Zn II  ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn II  ions, giving a zigzag chain along the  b  axis. Adjacent chains are connected by O—H⋯O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridine­aldoxime mol­ecule is located; this mol­ecule is linked by O—H⋯O and O—H⋯N hydrogen bonds to the zigzag chain.

acta crystallographica. section e

catena-Poly[[[bis(4-pyridinealdoxime-κN1)zinc]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] 4-pyridinealdoxime monosolvate]