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The title layered polymer, [Co(N 3 ) 2 (C 7 H 10 N 2 ) 2 ]  n  , contains Co II , azide and 4-(dimethyl­amino)­pyridine (4-DMAP) species with site symmetries  m 2 m , 2 and  m , respectively. The Co 2+  ion adopts an octa­hedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co II  atoms are connected by two bridging azide ligands, resulting in a chain parallel to the  c  axis.

catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]

catena-Poly[[bis[4-(dimethylamino)pyridine-κN¹]cobalt(II)]-di-μ-azido-κ⁴N¹:N³]