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In the title compound, [Sm(C 9 I 3 O 6 )(C 3 H 7 NO) 3 ]  n  , the Sm III  atom is coordinated by nine O atoms,  viz.  six carboxyl­ate O atoms from three 2,4,6-triiodobenzene-1,3,5-tricarboxyl­ate (I 3 BTC) ligands and three O atoms from three  N , N -dimethyl­formamide (DMF) mol­ecules. Each I 3 BTC ligand bridges three Sm III  atoms, generating a three-dimensional metal-organic framework structure. The asymmetric unit contains one Sm III  ion and one I 3 BTC anion, both situated on a threefold axis, and one DMF mol­ecule in a general position.

Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]

Poly[tris(dimethylformamide)(μ₃-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]