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In the title complex, [Ni(C 9 H 5 O 6 ) 2 (C 11 H 10 N 4 ) 2 ]·8H 2 O, the Ni II  ion exhibits site symmetry 2. It has a distorted octa­hedral coordination defined by two N atoms from two symmetry-related 1-[(1 H -benzimidazol-1-yl)meth­yl]-1 H -imidazole ligands and four O atoms from two symmetry-related 3,5-dicarb­oxy­benzoate anions. In the crystal, the complex mol­ecules and solvent water mol­ecules are linked  via  O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, forming a three-dimensional structure. There are also a number of C—H⋯O inter­actions present.

acta crystallographica. section e

Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN3}bis(3,5-dicarboxybenzoato-κ2O1,O1′)nickel(II) octahydrate