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The title compound, C 12 H 10 N 2 O, a second monoclinic poly­morph of ( E )-phen­yl(pyridin-2-yl)methanone oxime crystallizes in the space group  P 2 1 / n  ( Z  = 4). The previously reported polymorph [Taga  et al.  (1990  ▶ ).  Acta Cryst . C 46 , 2241–2243] occurs in the space group  C 2/ c  ( Z  = 8). In the crystal, pairs of bifurcated O—H⋯(N,O) hydrogen bonds link the mol­ecules into inversion dimers. The dimers are linked by C—H⋯π inter­actions, forming a linear arrangement. The dihedral angle between the pyridine and phenyl rings is 67.70 (8)°.

A second monoclinic polymorph of (E)-phenyl(pyridin-2-yl)methanone oxime