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In the title compound, {[Mn(C 15 H 8 O 7 )(C 10 H 8 N 2 )(H 2 O) 3 ]·C 10 H 8 N 2 ·2H 2 O}  n  , the bridging mode of the coordinating 4,4′-bipyridine ligands leads to the formation of polymeric zigzag chains parallel to [0-11]. The chains are separated by 4,4′-bipyridine and water solvent mol­ecules. Within a chain, the Mn II  atom is six-coordinated by two N atoms of the bridging 4,4′-bipyridine ligands, three water O atoms and one carboxyl­ate O atom of a single deprotonated 3-(4-carb­oxy­phen­oxy)phthalic acid ligand. Both coordinating and solvent 4,4′-bipyridine mol­ecules are situated on centres of inversion. An intricate network of O—H⋯O and O—H⋯N hydrogen bonds involving the carb­oxy group, the coordinating water mol­ecules and the two types of solvent mol­ecules leads to the formation of a three-dimensional network.

acta crystallographica. section e

catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO2]manganese(II)]-μ-4,4′-bipyridine-κ2N:N′] 4,4′-bipyridine monosolvate dihydrate]