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In the neutral mononuclear iridium(III) title compound, [Ir(C 8 H 7 ClNO)(C 11 H 8 N) 2 ], the Ir III  atom adopts an octa­hedral geometry, and is coordinated by two 2-phenyl­pyridyl ligands and one anionic 4-chloro­acetanilide ligand. The 2-phenyl­pyridyl ligands are arranged in a  cis - C , C ′ and  cis - N , N ′ fashion. Each 2-phenyl­pyridyl ligand forms a five-membered ring with the Ir III  atom. The 2-phenyl­pyridyl planes are perpendicular to each other [dihedral angle = 89.9 (1)°]. The Ir—C and Ir—N bond lengths are comparable to those reported for related iridium(III) 2-phenyl­pyridyl complexes. The remaining two coordination sites are occupied by the amidate N and O atoms, which form a four-membered ring with the iridium atom (Ir—N—C—O). The amidate plane is nearly perpendicular to both 2-phenyl­pyridyl ligands [dihedral angles = 87.8 (2) and 88.3 (2)°].

(4-Chloroacetanilido-κ2N,O)bis[2-(pyridin-2-yl)phenyl-κ2C1,N]iridium(III)

(4-Chloroacetanilido-κ²N,O)bis[2-(pyridin-2-yl)phenyl-κ²C¹,N]iridium(III)