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The binuclear title complex, [Co 2 (C 18 H 26 N 4 O 12 )(H 2 O) 2 ]·4H 2 O, lies about a centre of inversion, the Co II  atom being coordinated in a distorted octa­hedral arrangement defined by one water mol­ecule and N 2 O 3  donors derived from one end of a 6,9-bis(carboxylatomethyl)-3,12-bis(car­boxy­methyl)-3,6,9,12-tetraaza­tetradecanedioate (H 2 TTHA 4− ) tetra­anion. In the crystal, numerous O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.

[μ-6,9-Bis(carboxylatomethyl)-3,12-bis(carboxymethyl)-3,6,9,12-tetraazatetradecanedioato]bis[aquacobalt(II)] tetrahydrate