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In the title compound, [Cu 3 I 3 (C 5 H 5 NS) 3 ]  n  , a polymeric structure is formed along [100] through bridging iodide and pyridine-2-thione ligands. The metal atoms are engaged in [Cu 3 S 3 ] and [Cu 2 S 2 ] rings sharing Cu—S edges, with the [Cu 2 S 2 ] rings located about inversion centers. Cu I  atoms bridged by iodide ions exhibit the shortest Cu⋯Cu separation in the polymer [2.8590 (14) Å]. The three independent Cu I  atoms all display distorted tetra­hedral coordination geometries.

acta crystallographica. section e

catena-Poly[μ2-iodido-diiodidobis(μ3-pyridine-2-thione-κ3S:S:S)(μ2-pyridine-2-thione-κ2S:S)tricopper(I)]