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In the title compound, (C 7 H 11 N 2 ) 3 [Fe(NCS) 6 ]·H 2 O, the Fe III  cation is coordinated by six terminal  N -bonded thio­cyanate anions into a discrete threefold negatively charged complex. Charge balance is achieved by three protonated 4-(dimethyl­amino)­pyridine cations. The asymmetric unit consists of one Fe III  cation, six thio­cyanate anions, three 4-(dimethyl­amino)­pyridinium cations and one water mol­ecule, all of them located in general positions.

Tris[4-(dimethylamino)pyridinium] hexakis(thiocyanato-κN)ferrate(III) monohydrate