English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Reaction between [Fe2(μ-S2)(CO)6] and [Ca(thf)4(dpp-BIAN)] [dpp-BIAN = 1,2-bis-(2,6-diisopropyl-phenyl-imino)-acenaphthene and thf = tetra-hydro-furan] proceeds as a redox process via a two-electron reduction of [Fe2(μ-S2)(CO)6] and a two-electron oxidation of (dpp-BIAN)(2-), resulting in the formation of the title heterometallic trinuclear cluster, [CaFe2(μ3-S)2(C4H8O)4(CO)6], and neutral dpp-BIAN. In the cluster, the Ca(II) atom is connected to two S atoms of an Fe2S2 core [Ca-S = 2.7463 (8) and 2.7523 (8) Å]. No Fe-Ca bonds are formed [Fe⋯Ca = 3.6708 (6) and 3.5802 (6) Å]. There are five close C-H⋯O-C contacts in the crystal structure.

acta crystallographica. section e

Hexacarbonyl-2κ3C,3κ3C-di-μ3-sulfido-tetrakis(tetrahydrofuran-1κO)calciumdiiron(II)(Fe—Fe)