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The asymmetric unit of the title hydrated co-crystal, 2C 19 H 13 N 5 ·C 6 H 10 O 4 ·4H 2 O, consists of one 2,6-bis­(1 H -benzimidazol-2-yl)pyridine mol­ecule, half of an adipic acid mol­ecule (bis­ected by an inversion center) and two water solvates. In the crystal, N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds and π–π inter­actions [centroid–centroid distances = 3.769 (2) and 3.731 (2) Å] form a three-dimensional supra­molecular structure.

Adipic acid–2,6-bis(1H-benzimidazol-2-yl)pyridine–water (1/2/4)