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The title compound, (C 4 H 14 N 2 ) 2 [Mo 2 O 4 F 6 ]·H 2 O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO 3 , HF, 1,4-diamino­butane (dab), water and ethyl­ene glycol. The structure consists of [Mo 2 O 4 F 6 ] 4−  anionic dimers containing strongly distorted MoO 3 F 3  octa­hedra (with twofold symmetry), diprotonated dab cations and water mol­ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N—H⋯O, N—H⋯F and O—H⋯F inter­actions.

Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate