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The title compound, [Hg 5 Br 10 (C 7 H 8 N 2 O) 2 ]  n  , contains two μ 3 -bridging Br atoms, six μ 2 -bridging Br atoms and two terminal Br atoms. One Hg II  atom, lying on an inversion center, adopts a distorted octa­hedral geometry defined by six Br atoms. Two Hg II  atoms adopt a distorted square-pyramidal geometry by five Br atoms and the other two Hg II  atoms have a distorted tetra­hedral geometry by two N atoms from a chelating  O -methyl pyridine-2-carboximidate ligand and two Br atoms. The Br atoms link the Hg II  atoms into a ribbon structure along [100].

acta crystallographica. section e

catena-Poly[di-μ3-bromido-hexa-μ2-bromido-dibromidobis(O-methyl pyridine-2-carboximidate-κ2N,N′)pentamercury(II)]