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In the centrosymmetric dinuclear title Ag I  compound, [Ag 2 (C 6 H 6 N 2 O) 4 ](NO 3 ) 2 , the aromatic amine-coordinated Ag I  atom is further bridged by two hydroxyl­amine mol­ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound mol­ecules  via  O—H⋯O hydrogen bonds, generating a chain running along the  a -axis direction.

acta crystallographica. section e

Bis[μ-(E)-N-(pyridin-3-ylmethylidene)hydroxyamine]-κ2N1:N3;κ2N3:N1-bis{[(E)-N-(pyridin-3-ylmethylidene-κN)hydroxyamine]silver(I)} dinitrate